复合乳化剂制备乳化炸药的热分解行为

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复合乳化剂制备乳化炸药的热分解行为
Thermal Decomposition Behavior of Emulsion Explosives Prepared by Multiple Emulsion

摘要：  
用T154、T155和Span80制备复合乳化剂,采用DSC-TG联用技术研究了用复合乳化剂制备的4种乳化炸药的热分解行为,用Kissinger法、Ozawa法及Satava-Sestak法计算其热分解动力学参数.通过3种方法结果的比较得到4种乳化炸药热分解反应的动力学参数和最概然机理函数.
Abstract：?  
Multiple emulsifier was prepared by T154,T155 and Span80. The thermal decomposition behaviors of four kinds of emulsion explosives prepared by multiple emulsifier agents were studied by DSC-TG technique. The thermal decomposition kinetic parameters of these emulsion explosives were calculated by Kissinger,Ozawa and atava-Sestak methods. Their thermal decomposition kinetic parameters and the most probable mechanism function were obtained by comparison of calculated results by three methods.
doi：  10.3969/j.issn.1007-7812.2009.03.002  
作者：  罗宁  李晓杰  王小红  张晓军   
Author：  LUO Ning    LI Xiao-jie    WANG Xiao-hong    ZHANG Xiao-jun   
作者单位：  大连理工大学工业装备结构分析国家重点实验室工程力学系,辽宁,大连,116024  
刊  名：  火炸药学报ISTICPKU  
Journal：  CHINESE JOURNAL OF EXPLOSIVES & PROPELLANTS  
年，卷(期)：  2009, 32(3)  
分类号：  TJ55  TQ564  
关键词：  物理化学  乳化炸药  复合乳化剂  热分解特性  动力学计算  
Keywords：  physical chemistryemulsion explosivemultiple emulsionthermal decomposition characteristicsdynamic calculation  
机标分类号：  TP3 TN9  
在线出版日期：  2009年8月27日  
基金项目：  国家自然科学基金  

原文网址：

1. http://d.wanfangdata.com.cn/Periodical/hzyxb200903002

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